Big Breakthrough for “Massless” Energy Storage: Structural Battery That Performs 10x Better Than All Previous Versions
TOPICS:Battery Technology,Chalmers University Of Technology,Energy,Materials Science,Popular
By CHALMERS UNIVERSITY OF TECHNOLOGY MARCH 24, 2021
Structural battery composites cannot store as much energy as lithium-ion batteries, but have several characteristics that make them highly attractive for use in vehicles and other applications. When the battery becomes part of the load bearing structure, the mass of the battery essentially ‘disappears’. Credit: Yen Strandqvist/Chalmers University of Technology.
Researchers from Chalmers University of Technology have produced a structural battery that performs ten times better than all previous versions. It contains carbon fiber that serves simultaneously as an electrode, conductor, and load-bearing material. Their latest research breakthrough paves the way for essentially ’massless’ energy storage in vehicles and other technology.
The batteries in today’s electric cars constitute a large part of the vehicles’ weight, without fulfilling any load-bearing function. A structural battery, on the other hand, is one that works as both a power source and as part of the structure – for example, in a car body. This is termed ‘massless’ energy storage, because in essence the battery’s weight vanishes when it becomes part of the load-bearing structure. Calculations show that this type of multifunctional battery could greatly reduce the weight of an electric vehicle.
The development of structural batteries at Chalmers University of Technology has proceeded through many years of research, including previous discoveries involving certain types of carbon fiber. In addition to being stiff and strong, they also have a good ability to store electrical energy chemically. This work was named by Physics World as one of 2018’s ten biggest scientific breakthroughs.
The first attempt to make a structural battery was made as early as 2007, but it has so far proven difficult to manufacture batteries with both good electrical and mechanical properties.
Doctor Johanna Xu with a newly manufactured structural battery cell in Chalmers’ composite lab, which she shows to Leif Asp. The cell consists of a carbon fiber electrode and a lithium iron phosphate electrode separated by a fiberglass fabric, all impregnated with a structural battery electrolyte for combined mechanical and electrical function. Three structural batteries have been connected in series and laminated as part of a larger composite laminate. Each structural battery cell has a nominal voltage of 2.8 V. The laminate has a total voltage of 8.4 V and a stiffness in the plane of just over 28 GPa. Credit: Marcus Folino, Chalmers University of Technology.
But now the development has taken a real step forward, with researchers from Chalmers, in collaboration with KTH Royal Institute of Technology in Stockholm, presenting a structural battery with properties that far exceed anything yet seen, in terms of electrical energy storage, stiffness and strength. Its multifunctional performance is ten times higher than previous structural battery prototypes.
The battery has an energy density of 24 Wh/kg, meaning approximately 20 percent capacity compared to comparable lithium-ion batteries currently available. But since the weight of the vehicles can be greatly reduced, less energy will be required to drive an electric car, for example, and lower energy density also results in increased safety. And with a stiffness of 25 GPa, the structural battery can really compete with many other commonly used construction materials.
“Previous attempts to make structural batteries have resulted in cells with either good mechanical properties, or good electrical properties. But here, using carbon fiber, we have succeeded in designing a structural battery with both competitive energy storage capacity and rigidity,” explains Leif Asp, Professor at Chalmers and leader of the project.
Super light electric bikes and consumer electronics could soon be a reality
The new battery has a negative electrode made of carbon fiber, and a positive electrode made of a lithium iron phosphate-coated aluminum foil. They are separated by a fiberglass fabric, in an electrolyte matrix. Despite their success in creating a structural battery ten times better than all previous ones, the researchers did not choose the materials to try and break records – rather, they wanted to investigate and understand the effects of material architecture and separator thickness.
Now, a new project, financed by the Swedish National Space Agency, is underway, where the performance of the structural battery will be increased yet further. The aluminum foil will be replaced with carbon fiber as a load-bearing material in the positive electrode, providing both increased stiffness and energy density. The fiberglass separator will be replaced with an ultra-thin variant, which will give a much greater effect – as well as faster charging cycles. The new project is expected to be completed within two years.
Leif Asp, who is leading this project too, estimates that such a battery could reach an energy density of 75 Wh/kg and a stiffness of 75 GPa. This would make the battery about as strong as aluminum, but with a comparatively much lower weight.
Leif Asp, Professor at the Department of Industrial and Materials Sciences, Chalmers University of Technology. He published his first paper on structural batteries in 2010, and has now succeeded in demonstrating multifunctional performance ten times higher than in any previous structural battery prototype. Credit: Marcus Folino, Chalmers University of Technology.
“The next generation structural battery has fantastic potential. If you look at consumer technology, it could be quite possible within a few years to manufacture smartphones, laptops or electric bicycles that weigh half as much as today and are much more compact,” says Leif Asp.
And in the longer term, it is absolutely conceivable that electric cars, electric planes and satellites will be designed with and powered by structural batteries.
“We are really only limited by our imaginations here. We have received a lot of attention from many different types of companies in connection with the publication of our scientific articles in the field. There is understandably a great amount of interest in these lightweight, multifunctional materials,” says Leif Asp.
Reference: “A Structural Battery and its Multifunctional Performance” by Leif E. Asp, Karl Bouton, David Carlstedt, Shanghong Duan, Ross Harnden, Wilhelm Johannisson, Marcus Johansen, Mats K. G. Johansson, Göran Lindbergh, Fang Liu, Kevin Peuvot, Lynn M. Schneider, Johanna Xu and Dan Zenkert, 27 January 2021, Advanced Energy & Sustainability Research.
More about: The research on structural batteries
The structural battery uses carbon fiber as a negative electrode, and a lithium iron phosphate-coated aluminum foil as the positive electrode. The carbon fiber acts as a host for the lithium and thus stores the energy. Since the carbon fiber also conducts electrons, the need for copper and silver conductors is also avoided – reducing the weight even further. Both the carbon fiber and the aluminum foil contribute to the mechanical properties of the structural battery. The two electrode materials are kept separated by a fiberglass fabric in a structural electrolyte matrix. The task of the electrolyte is to transport the lithium ions between the two electrodes of the battery, but also to transfer mechanical loads between carbon fibers and other parts.
The project is run in collaboration between Chalmers University of Technology and KTH Royal Institute of Technology, Sweden’s two largest technical universities. The battery electrolyte has been developed at KTH. The project involves researchers from five different disciplines: material mechanics, materials engineering, lightweight structures, applied electrochemistry and fiber and polymer technology. Funding has come from the European Commission’s research program Clean Sky II, as well as the US Airforce.